The Multiple Recycling Process of Polypropylene Composites with Glass Fiber in Terms of Grinding Efficiency and Selected Properties of Recirculated Products

从研磨效率和再生产品的部分性能角度,探讨了含玻璃纤维聚丙烯复合材料的多次回收工艺

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Abstract

This study comprehensively discusses the effect of multiple material recycling (five recycling cycles with the same technological conditions: injection molding → grinding → drying → injection molding → …) of commercial polypropylene-glass fiber composites (PPGF) (PP + 10, 20 and 30 wt.% GF) on the performance of the grinding process and the granulometric characteristics of the obtained regrinds, as well as selected surface, mechanical and thermal properties of the composites. An increase in mass (E(m)) and volume (E(v)) grinding efficiency was confirmed, along with an increase in GF content in the composite and the number of recycling cycles. Both the GF additive and the number of recycling cycles contributed to the deterioration of the aesthetic qualities of the composites (darkening and reduction in gloss). Slight changes in the surface hardness of the test materials were observed as a function of the number of recycling cycles, from 3 to 4% after five recycling cycles. The adverse effect of multiple recycling on the mechanical and thermal properties of PP and PPGF composites has been confirmed. The occurrence and increase in carbonyl index (CI) values, as a function of multiples recycling, was confirmed for a composite containing 20 wt.% GF (CI in the range from 0.045 to 0.092) and for PPGF containing 30 wt.% GF (CI in the range from 0.193 to 0.272). The effect of multiple material recycling on the glass fiber structure in the tested composites was also investigated using scanning electron microscopy (SEM) and optical microscopy. The issues of grinding and changes in the surface properties of PPGF composites in multiple material recycling processes discussed in this article may constitute a source of practical knowledge that will contribute to increasing the use of this type of secondary composite in industrial plastics processing processes.

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