Excellent Energy Storage Performance in Epoxy Resin Dielectric Polymer Films by a Facile Hot-Pressing Method

通过简便的热压方法在环氧树脂介电聚合物薄膜中实现优异的储能性能

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作者:Zhe Pan, Minmin Mao, Bin Zhang, Zhongyu Li, Kaixin Song, Hai-Feng Li, Zhu Mao, Dawei Wang

Abstract

Epoxy resin (EP), as a kind of dielectric polymer, exhibits the advantages of low-curing shrinkage, high-insulating properties, and good thermal/chemical stability, which is widely used in electronic and electrical industry. However, the complicated preparation process of EP has limited their practical applications for energy storage. In this manuscript, bisphenol F epoxy resin (EPF) was successfully fabricated into polymer films with a thickness of 10~15 μm by a facile hot-pressing method. It was found that the curing degree of EPF was significantly affected by changing the ratio of EP monomer/curing agent, which led to the improvement in breakdown strength and energy storage performance. In particular, a high discharged energy density (Ud) of 6.5 J·cm-3 and efficiency (η) of 86% under an electric field of 600 MV·m-1 were obtained for the EPF film with an EP monomer/curing agent ratio of 1:1.5 by hot pressing at 130 °C, which indicates that the hot-pressing method could be facilely employed to produce high-quality EP films with excellent energy storage performance for pulse power capacitors.

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