Bis(cyclo-hexyl-ammonium) tetra-chlorido-(oxalato)stannate(IV)

双(环己基铵)四氯化草酸锡酸盐 (IV)

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作者:Modou Sarr, Aminata Diasse-Sarr, Waly Diallo, Laurent Plasseraud, Hélène Cattey

Abstract

The title salt, (C6H14N)2[Sn(C2O4)Cl4], was obtained as a by-product from the reaction between 2C6H14N(+)·C2O4 (2-)·1.5H2O and SnCl2·2H2O. The cyclo-hexyl-ammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl4 moiety, resulting in a distorted octa-hedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N-H⋯O and N-H⋯Cl inter-actions into a layered arrangement parallel to (100).

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