Abstract
A novel oxygen evolution reaction (OER) electrocatalyst was prepared by a synthesis strategy consisting of the solvothermal growth of Ni(3)S(2) nanostructures on Ni foam, followed by hydrothermal incorporation of Fe species (Fe-Ni(3)S(2)/Ni foam). This electrocatalyst displayed a low OER overpotential of 230 mV at 100 mA·cm(-2), a low Tafel slope of 43 mV·dec(-1), and constant performance at an industrially relevant current density (500 mA·cm(-2)) over 100 h in a 1.0 M KOH electrolyte, despite a minor loss of Fe in the process. Based on a detailed characterization by (in situ) Raman spectroscopy, (quasi-in situ) XPS, SEM, TEM, XRD, ICP-AES, EIS, and C(dl) analysis, the high OER activity and stability of Fe-Ni(3)S(2)/Ni foam were attributed to the nanostructuring of the surface in the form of stable nanosheets and to the combination of Ni(3)S(2) granting suitable electrical conductivity with newly formed NiFe-based (oxy)hydroxides at the surface of the material providing the active sites for OER.