Abstract
The range of lubricant applications has broadened to include multiple sectors, aiming to optimize the operational efficiency of mechanical systems. Given their adaptable friction-reducing properties, lubricants have recently been incorporated into energy harvesting technologies such as triboelectric nanogenerators (TENGs). In such devices, lubricants are essential for mitigating wear, facilitating heat dissipation, eliminating contaminants, and prolonging the service life of mechanically actuated energy harvesters. Notably, emerging developments in sliding and rotational-mode TENGs leverage lubricants to improve electrical output while reducing interface degradation. However, despite significant potential, TENGs still face inherent challenges, including interface friction and energy losses from air breakdown. Recent research indicates that these drawbacks can be effectively addressed by the intentional use of polymer-based lubricants, which contribute to maintaining micro/nanostructured surfaces and minimizing air breakdown, thereby enhancing charge storage capability and increasing device robustness. This review systematically examines the categories, physicochemical attributes, and operational roles of polymeric lubricants used in TENG technology. It underscores their combined function is both primary and support materials to augment triboelectric efficiency. In addition, the article assesses how different lubricants impact device performance and durability, providing a critical analysis of their suitability based on the operational benchmarks of lubricant-embedded TENG configurations.