Protease-Activated Receptor 1 as an Endogenous Model of Peptidergic Gαq-Gα12-Biased G Protein Signaling

蛋白酶激活受体 1 作为肽能 Gαq-Gα12 偏向性 G 蛋白信号的内源性模型

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Abstract

G protein-coupled receptors (GPCRs) are the most widely targeted class of signaling proteins, comprising ~30% of FDA-approved drugs. Their therapeutic potential arises from their ability to translate diverse extracellular cues into intracellular signals via G proteins, arrestins, and other effectors. This signaling versatility creates opportunities for functional selectivity, where ligands preferentially engage particular pathways. However, biased agonists have shown limited clinical success. We sought an endogenous receptor with native functional selectivity as a model to understand mechanisms of bias. Protease-activated receptor 1 (PAR1) is a potential model. Thrombin and activated protein C (aPC) cleave PAR1 at Arg41 and Arg46, respectively, creating distinct tethered peptide ligands. Thrombin cleavage drives canonical Gαq- and Gα12/13-dependent prothrombotic and barrier-disruptive signaling, whereas aPC cleavage has been associated with anticoagulant, cytoprotective, and anti-inflammatory signaling. However, PAR1's transducer-wide coupling profile, transcriptional consequences, and physiological outputs remain incompletely characterized. We integrate transducer-wide biosensor assays (TRUPATH, TGFα shedding, PRESTO-Tango), analysis of a PAR1 ± thrombin TRE-MPRA dataset with targeted TRE luciferase validation using thrombin and aPC, and platelet activation studies to define how protease identity reshapes signaling from proximal transducer engagement to physiological output. Thrombin produced robust PAR1 coupling to Gαq and Gα12, whereas aPC produced detectable coupling only to Gα12. Neither protease generated detectable β-arrestin-2 recruitment in PRESTO-Tango. Both proteases supported dose-dependent TGFα shedding that was insensitive to FR900359, indicating that Gα12-linked signaling is sufficient for this effector readout. A PAR1 ± thrombin TRE-MPRA dataset identified thrombin-responsive regulatory elements and nominated NFκB1 and THRB as candidate reporters. Luciferase assays showed NFκB1 is thrombin-induced and fully blocked by FR900359, whereas THRB is induced by both thrombin and aPC and is FR900359-insensitive. In primary human platelets, thrombin, but not aPC, induced P-selectin expression. Thrombin responses were suppressed by FR900359, supporting a Gαq requirement for these platelet activation markers. Together, these findings support PAR1 as an endogenous model of protease-dependent functional selectivity that, in our heterologous assay systems, separates signaling along a Gαq-versus-Gα12 axis, thus providing a framework for future technologies, such as high-throughput tethered-peptide evolution platforms, to understand the principles of G protein selectivity across GPCRs.

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