Structure Property-Application Relationships of Spinel Ferrite Nanoparticles: From Synthesis to Functional Systems

尖晶石型铁氧体纳米粒子的结构-性质-应用关系:从合成到功能体系

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Abstract

This review article provides a systematic analysis of synthesis methods, structural characteristics, and functional properties of spinel-structured ferrite nanoparticles (MFe(2)O(4)). The physicochemical principles, advantages, and limitations of various synthesis techniques-including co-precipitation, combustion, sol-gel, thermal decomposition, hydrothermal, solvothermal, microwave-assisted, sonochemical, electrochemical, and solid-state reaction methods-are comparatively discussed. The influence of synthesis parameters on crystal structure, morphology, and cation distribution between tetrahedral and octahedral sites, as well as on magnetic, dielectric, and optical properties, is critically analyzed. Furthermore, the capabilities of characterization techniques such as X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS), Fourier-transform infrared spectroscopy (FTIR), FT-Raman spectroscopy, dielectric measurements, and magnetic measurements for investigating spinel ferrites are comprehensively summarized. Finally, the high potential of spinel ferrite nanoparticles for applications in electronics, microwave devices, water treatment, catalysis, sensors, and biomedical fields is highlighted.

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