Deep-ultraviolet transparent conducting SrSnO(3) via heterostructure design

通过异质结构设计制备深紫外透明导电SrSnO(3)

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Abstract

Exploration and advancements in ultrawide bandgap (UWBG) semiconductors are pivotal for next-generation high-power electronics and deep-ultraviolet (DUV) optoelectronics. Here, we used a thin heterostructure design to facilitate high conductivity due to the low electron mass and relatively weak electron-phonon coupling, while the atomically thin films ensured high transparency. We used a heterostructure comprising SrSnO(3)/La:SrSnO(3)/GdScO(3) (110), and applied electrostatic gating, which allow us to effectively separate charge carriers in SrSnO(3) from dopants and achieve phonon-limited transport behavior in strain-stabilized tetragonal SrSnO(3). This led to a modulation of carrier density from 10(18) to 10(20) cm(-3), with room temperature mobilities ranging from 40 to 140 cm(2) V(-1) s(-1). The phonon-limited mobility, calculated from first principles, closely matched experimental results, suggesting that room temperature mobility could be further increased with higher electron density. In addition, the sample exhibited 85% optical transparency at a 300-nm wavelength. These findings highlight the potential of heterostructure design for transparent UWBG semiconductor applications, especially in DUV regime.

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