Mineralogy and Stable Isotopes of Tetradymite from the Dashuigou Tellurium Deposit, Tibet Plateau, Southwest China

中国西南青藏高原大水沟碲矿床四方碲的矿物学和稳定同位素

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Abstract

Due to the very limited quantity of associated tetradymite, both mineralogical and geochemical research on tetradymite is scarce and incomplete. By taking advantage of the discovery of the Dashuigou tellurium deposit in Tibet Plateau, the authors conducted mineralogical studies on tetradymite. The authors present new mineralogical data including reflectance, micro-pressure hardness, chemical compositions focusing on its chemical formula Bi(2.00)Te(1.89)S(0.95~1.00), unit cell parameters (a = 4.239 Å, c = 29.595 Å) and lattice parameters (a = 10.172 Å, v = 154.391 Å(3)), pyroelectricity (N type), and stable isotopes including sulfur and lead. The authors find that: δ(34)S‰ of tetradymite varies between -0.5~2.1 with a 15-sample average of 0.56, similar to that of meteorites and rocks from the mantle, indicating that the sulfur is from the mantle; lead isotopes of the tetradymite formed in the late metallogenic epoch is different from that of both pyrite and pyrrhotite formed in the early metallogenic epoch, further indicating that the three minerals formed in different metallogenic epochs; lead isotope compositions reveal that tellurium ore bodies emplaced in a quick process mainly in the form of ore magma; lead of the deposit is primarily from the mantle with some captured from the Earth's crust. These findings help fill in large gaps of information for the mineral tetradymite.

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