Abstract
It is well known that obtaining efficient carbamazepine degradation materials or rapid carbamazepine-removal methods is still a challenge in the field of environmental remediation. Hence, the present study aimed to concurrently address these issues by combining a self-driven, heterostructured and low-cost biomass-templated urchin-like Janus micromotor catalyst for highly efficient carbamazepine degradation. The catalyst could autonomously move in a circle-like motion pattern via O2 bubbles generated from the Mn3O4-catalyzed decomposition of H2O2 with a velocity of 223.5 ± 7.0 μm s-1 in 1% H2O2. Benefiting from the well-structured heterojunction at the interface of C3N4 and Mn3O4, carbamazepine (CBZ) was degraded by 61% in 100 min under sunlight irradiation. In addition, density functional theory calculation results proved that the formation of the heterojunction structure promoted the generation of photo-generated carriers. Thus, the presented method provides a promising pathway for the rational construction and preparation of movable catalysts for the efficient removal of organic pollutants from wastewater.