Development of cellulose acetate poly acrylonitrile (CAPA)-SiC/epoxy coating to mitigate corrosion of copper in chloride containing solutions

开发醋酸纤维素聚丙烯腈 (CAPA)-SiC/环氧涂层以减轻含氯化物溶液中铜的腐蚀

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作者:Nehal Bargout, Abd El-Hady B Kashyout, Magdy A M Ibrahim, Ahmed El Nemr

Abstract

A new conducting polymer of the cellulose acetate poly acrylonitrile (CAPA)-SiC composite was produced using an in situ oxidative polymerization technique in an aqueous medium. SiC was synthesized from Cinachyrella sp. as a source of carbon and silicon at 1200 °C under an argon atmosphere via a catalytic reduction process. The structure and morphology of the CAPA-SiC composite were characterized using surface area studies (BET), X-ray diffraction (XRD), Fourier transformation infrared spectroscopy (FT-IR), and surface morphology (SEM & TEM). To protect copper, the produced CAPA-SiC composite was mixed with commercial epoxy paint using a casting technique, and the copper surface was coated with the three components of the CAPA-SiC/epoxy paint mixture. The corrosion inhibition improvement of the CAPA-SiC/paint coating was assessed using electrochemical impedance spectroscopy followed by Tafel polarization measurements in a 3.5 wt% NaCl solution. The corrosion protection ability of the CAPA-SiC/epoxy coating was found to be outstanding at 97.4% when compared to that of a CAPA/paint coating. SEM and XRD were used to illustrate the coating on the copper surface.

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