Insight on the Mechanical Properties of Facile Hydrophobic-Barrier-Patterned Bacterial Nanocellulose via Self-Bonding Mechanism

通过自键合机制深入了解简易疏水屏障图案化细菌纳米纤维素的力学性能

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Abstract

Enhancing the mechanical and structural properties of bacterial nanocellulose (BNC) is key to its use in sustainable nanocomposites. This study employed a hot-press drying method with hydrophobic barriers, folding BNC into four layers and pressing with carbon fiber and Teflon sheets. At 120 °C, carbon fiber-pressed BNC achieved a tensile strength of 43.91 N/mm(2), 13.84% higher than oven-dried samples and 43.87% higher than Teflon-pressed samples. Scanning electron microscopy (SEM), KLA-Zeta, and atomic force microscopy (AFM) analyses revealed improved self-bonding and surface roughness. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) confirmed increased crystallinity and altered hydrogen bonding, enhancing stiffness and structural stability. Optical and thermal tests showed carbon fiber-pressed BNC was less transparent with moderate heat resistance, while Teflon-treated samples remained clear with higher thermal stability. These findings demonstrate that patterned hot pressing strengthens BNC's self-bonding, advancing its potential for use in structural nanocomposites, flexible electronics, and biocompatible scaffolds.

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