Abstract
Lignin, the most abundant aromatic polymer in nature, plays a critical role in lignocellulosic biomasses by providing structural support. However, its presence complicates the industrial exploitation of these materials for biofuels, paper production and other high-value compounds. Annually, the industrial extraction of lignin reaches an estimated 225 million tons, yet only a fraction is recovered for reuse, with most incinerated as low-value fuel. The growing interest in lignin potential has sparked research into sustainable recovery methods from lignocellulosic agro-industrial wastes. This review examines the chemical, physical and physicochemical processes for isolating lignin, focusing on innovative, sustainable technologies that align with the principles of a circular economy. Key challenges include lignin structural complexity and heterogeneity, which hinder its efficient extraction and application. Nonetheless, its properties such as high thermal stability, biodegradability and abundant carbon content place lignin as a promising material for diverse industrial applications, including chemical synthesis and energy generation. A structured analysis of advancements in lignin extraction, characterization and valorization offers insights into transforming this undervalued by-product into a vital resource, reducing reliance on non-renewable materials while addressing environmental sustainability.