Abstract
This review explores the development and application of the impregnation of graphene-based materials into polymeric coatings to enhance corrosion resistance. Derivatives of graphene, such as graphene oxide (GO) and reduced graphene oxide (rGO), have been increasingly integrated into polymer matrices to enhance polymers' mechanical, thermal, and barrier properties. Various synthesis approaches, viz., electrochemical deposition, chemical reduction, and the incorporation of functionalised graphene derivatives, have been explored for improving the dispersion and stability of graphene within polymers. These graphene-impregnated coatings have shown promising results in improving corrosion resistance by enhancing impermeability to corrosive agents and reinforcing mechanical strength under corrosive conditions. While the addition of graphene notably enhances coating performance, challenges remain in achieving uniform graphene dispersion and addressing the trade-offs between thickness and flexibility. This review highlights current advancements, limitations, and future directions, with a particular emphasis on optimising the synthesis techniques to maximise corrosion resistance while maintaining coating durability and economic feasibility.