Abstract
A supercapattery is a hybrid device that is a combination of a battery and a capacitor. Niobium sulfide (NbS), silver sulfide (Ag(2)S), and niobium silver sulfide (NbAg(2)S) were synthesized by a simple hydrothermal method. NbAg(2)S (50/50 wt% ratio) had a specific capacity of 654 C g(-1), which was higher than the combined specific capacities of NbS (440 C g(-1)) and Ag(2)S (232 C g(-1)), as determined by the electrochemical investigation of a three-cell assembly. Activated carbon and NbAg(2)S were combined to develop the asymmetric device (NbAg(2)S//AC). A maximum specific capacity of 142 C g(-1) was delivered by the supercapattery (NbAg(2)S//AC). The supercapattery (NbAg(2)S/AC) provided 43.06 W h kg(-1) energy density while retaining 750 W kg(-1) power density. The stability of the NbAg(2)S//AC device was evaluated by subjecting it to 5000 cycles. After 5000 cycles, the (NbAg(2)S/AC) device still had 93% of its initial capacity. This research indicates that merging NbS and Ag(2)S (50/50 wt% ratio) may be the best choice for future energy storage technologies.