Enhanced Stability, Superior Anti-Corrosive, and Tribological Performance of Al(2)O(3) Water-based Nanofluid Lubricants with Tannic Acid and Carboxymethyl Cellulose over SDBS as Surfactant

以单宁酸和羧甲基纤维素为表面活性剂的Al₂O₃水基纳米流体润滑剂比以SDBS为表面活性剂的润滑剂具有更高的稳定性、更优异的抗腐蚀性和摩擦学性能

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Abstract

In this research work, the stability, tribological, and corrosion properties of a water-based Al(2)O(3) nanofluid (0.5 wt%) formulated with tannin acid (TA) and carboxymethyl cellulose (CMC) as dispersants or surfactants were investigated. For comparative purposes, sodium dodecylbenzene sulfonate (SDBS) was also incorporated. The stability of the nanofluid was assessed through zeta potential measurements and photo-capturing, revealing the effectiveness of TA and CMC in preventing nanoparticle agglomeration. Tribological properties were examined using a pin-on-disk apparatus, highlighting the tribofilm of Al(2)O(3) that enhanced lubricating properties of the nanofluid by the SEM, resulting in reduced friction and wear of the contacting surfaces. Sample with the addition of both TA and CMC exhibited the best tribological performance, with a ~ 20% reduction in the friction coefficient and a 59% improvement in wear rate compared to neat nanofluid without TA and CMC(.) Additionally, the corrosion resistance of the nanofluids were evaluated via weight loss and electrochemical impedance spectroscopy. The nanofluid sample containing both TA and CMC exhibited the lowest corrosion rate, with 97.6% improvement compared to sample without them. This study provides valuable insights into the potential applications of TA and CMC-based Al(2)O(3) nanofluids as effective and environmentally friendly solutions for coolant or lubrication in cutting processes.

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