Effect of Sc and Zr Additions on Recrystallization Behavior and Intergranular Corrosion Resistance of Al-Zn-Mg-Cu Alloys

Sc和Zr添加对Al-Zn-Mg-Cu合金再结晶行为和晶间腐蚀性能的影响

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Abstract

The recrystallization and intergranular corrosion behaviors impacted by the additions of Sc and Zr in Al-Zn-Mg-Cu alloys are investigated. The stronger effect of coherent Al(3)(Sc(1-x)Zr(x)) phases on pinning dislocation resulted in a lower degree of recrystallization in Al-Zn-Mg-Cu-Sc-Zr alloy, while the subgrain boundaries can escape from the pinning of Al(3)Zr phases and merge with each other, bringing about a higher degree of recrystallization in Al-Zn-Mg-Cu-Zr alloy. A low degree of recrystallization promotes the precipitation of grain boundary precipitates (GBPs) with a discontinuous distribution, contributing to the high corrosion resistance of Al-Zn-Mg-Cu-Sc-Zr alloy in the central layer. The primary Al(3)(Sc(1-x)Zr(x)) phase promotes recrystallization due to particle-stimulated nucleation (PSN), and acts as the cathode to stimulate an accelerated electrochemical process between the primary Al(3)(Sc(1-x)Zr(x)) particles and GBPs, resulting in a sharp decrease of the corrosion resistance in the surface layer of Al-Zn-Mg-Cu-Sc-Zr alloy.

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