Modelling, Analysis, and Optimization of the Effects of Pulsed Electrophoretic Deposition Parameters on TiO(2) Films Properties Using Desirability Optimization Methodology

利用期望优化方法对脉冲电泳沉积参数对TiO(2)薄膜性能的影响进行建模、分析和优化

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Abstract

Titanium dioxide thin films immobilized over treated stainless steel were prepared using the pulsed electrophoretic deposition technique. The effects of process parameters (deposition time, applied voltage, initial concentration, and duty cycle) on photocatalytic efficiency and adhesion properties were investigated. To optimize the multiple properties of the thin film, a response surface methodology was combined with a desirability optimization methodology. Additionally, a quadratic model was established based on response surface analysis. The precision of the models was defined based on the analysis of variance (ANOVA), R(2), and the normal plot of residuals. Then, a desirability function was used to optimize the multiple responses of the TiO(2) thin film. The optimum values of applied voltage, catalyst concentration, duty cycle, and deposition time were 4 V, 16.34 g/L, 90% DC, and 150 s, respectively. Under these conditions, the decolorization efficiency of tested dye solution reached 82.75%. The values of critical charges L(C1), L(C2,) and L(C3) were 5.9 N, 12.5 N, and 16.7 N, respectively.

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