Effect of Graphene Oxide Addition on the Anticorrosion Properties of the Phosphate Coatings in Neutral and Acidic Aqueous Media

氧化石墨烯的添加对磷酸盐涂层在中性和酸性水性介质中防腐性能的影响

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Abstract

Graphene oxide (GO) is an advanced additive improving the properties of various types of coatings and intensifying the deposition process. In this work, GO is used as an additive to the traditional phosphating solution of the widely used Russian low-carbon steel 08YU (DC04). The anticorrosion properties of the obtained phosphate coatings were investigated in neutral (0.5 M NaCl) and acidified (0.1 M Na(2)SO(4) + 0.02 M H(2)SO(4)) aqueous solutions. Increasing the GO concentration in the phosphating solution to 0.3 g/L was found to improve the anticorrosion properties of the phosphate coatings in neutral NaCl solutions. At the same time, in acidified Na(2)SO(4) solutions, the corrosion rate of 08YU steel with phosphate coatings increased as a function of the GO concentration. It is assumed that a possible reason for various corrosive behavior is the influence of the GO plates distributed in the coating on the rate of the oxygen or hydrogen reduction reactions.

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