Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel

膨润土、铁氰化铜、丙烯酰胺和丙烯酸水凝胶双相杂化复合材料的合成及性能研究

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作者:Galymzhan Kulamkadyrovich Mamytbekov, Dmitry Anatol'evich Zheltov, Yernat Rashidovich Nurtazin

Abstract

This article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has been established that the sequential modification of bentonite with copper hexaferrocyanide and introduction of acrylamide and acrylic acid cross-linked copolymers into its volume by means of in situ polymerization promote the formation of a heterogeneous porous structure in the resulting hybrid material. The sorption abilities of prepared hybrid composite toward radionuclides of liquid radioactive waste (LRW) have been studied, and the mechanism for binding radionuclide metal ions with the components of the hybrid composition have been described.

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