Vacuum-Treated Brown Mesoporous TiO(2) Nanospheres with Tailored Defect Structures for Enhanced Photoresponsive Properties

真空处理棕色介孔TiO₂纳米球,具有可调控的缺陷结构,可增强其光响应性能

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Abstract

TiO(2) Nanospheres with a large surface area were synthesized via a hydrothermal reaction using titanium glycolate. The samples were subsequently subjected to different vacuum oven treatment times (2, 4, 6, and 8 h), resulting in Ti(3+) self-doping. Comprehensive characterization was performed using transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The synthesized TiO(2) Nanospheres exhibited significantly enhanced photocurrent and efficient photocatalytic activity under visible light irradiation, demonstrating their potential for applications in solar-driven water splitting. The results highlight the influence of Ti(3+) self-doping on improving the photoactivity and photosensitivity of the material.

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