Enhanced Antioxidant and Antibacterial Properties of Polybutylene Adipate-Terephthalate/Curcumin Composite Films Using Surface-Modified Cellulose Nanocrystals

利用表面改性纤维素纳米晶体增强聚己二酸丁二醇酯-对苯二甲酸丁二醇酯/姜黄素复合薄膜的抗氧化和抗菌性能

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Abstract

Polybutylene adipate-terephthalate (PBAT) offers a convincing ecological alternative to the traditional fossil-based plastics due to its biodegradability and robust mechanical properties. The objective of this study is to develop PBAT-based bio-composite films through incorporating functionalized cellulose nanocrystals (CNC) and curcumin (CUR). In order to improve the interfacial compatibility with the PBAT matrix and co-doping with CUR, CNC was modified using dodecyl succinic anhydride (D(x)CNC). In this ternary bio-composite system, CUR functioned as a bio-based antioxidant and antimicrobial agent. The presence of CUR also provides excellent UV-shielding properties, whereas the D(x)CNC effectively enhances the controlled release of CUR. The synergistic effect between D(x)CNC and CUR in boosting antimicrobial properties, with the inhibition values for E. coli and S. aureus reached 1.82 log CFU/cm(2) and 2.12 log CFU/cm(2), respectively. These findings indicate D(x)CNC/CUR/PBAT ternary composite films as a promising material for eco-friendly packaging products.

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