Near Room-Temperature Ferromagnetic Phase Achieved in 4d Ruthenate via Interfacial Ferrimagnetic Coupling and Octahedral Rotation Engineering

通过界面亚铁磁耦合和八面体旋转工程在4d钌酸盐中实现了接近室温的铁磁相

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Abstract

Transition metal oxides (TMOs) simultaneously possessing strong spin-orbit coupling, near room-temperature ferromagnetism, and excellent conductivity are scarce while they show great potential applications in oxide spintronics. Here, a TMO with all these features is reported, existing as an interfacial phase in the 4d Ca(0.5)Sr(0.5)RuO(3) layer sandwiched by two LaMnO(3) layers. This phase is well conductive and ferromagnetic in a wide temperature range, with the highest Curie temperature of ≈275 K among the 4d/5d-TMOs. Particularly, this interfacial phase shows a considerably improved saturation magnetization (≈2 µ(B)/Ru, twice that of the bulk counterpart), and a greatly reduced coercive force. All these features are highly desired by the application of spin-orbit torque. Due to the presence of strong spin-orbit coupling, such a Ca(0.5)Sr(0.5)RuO(3) interfacial phase exhibits a significantly larger anomalous Hall conductivity than the typical 3d oxide ferromagnet La(2/3)Sr(1/3)MnO(3) near room temperature. Analyses based on the techniques of X-ray magnetic circular dichroism, polarized-neutron reflectometry, and scanning transmission electron microscopy reveal a magnetic exchange interaction between the interfacial phases of Ca(0.5)Sr(0.5)RuO(3) and LaMnO(3) and an obvious expansion of the interfacial Mn─O─Mn bond angle, stabilizing the high-temperature ferromagnetic state of the CSRO/LMO interface.

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