Abstract
Optimizing electrocatalyst performance requires an atomic-scale understanding of surface state changes and how those changes affect activity and stability during the reaction. This is particularly important for the oxygen evolution reaction (OER) since the electrocatalytically active surfaces undergo substantial reconstruction and transformation. Herein, a multimodal method is employed that combines X-ray photoemission spectroscopy, transmission electron microscopy, atom probe tomography, operando surface-enhanced Raman spectroscopy with electrochemical measurements to examine the surface species formed on NiFe(2)O(4), P-doped NiFe(2)O(4) and Ni(1.5)Fe(1.5)O(4) upon OER cycling. The activated NiFe(2)O(4) and P-doped NiFe(2)O(4) exhibit a significantly lower Tafel slope (≈40 mV dec(-1)) than Ni(1.5)Fe(1.5)O(4) (≈90 mV dec(-1)), although oxyhydroxides are grown on all three Ni-Fe spinels during OER. This is likely attributed to the formation of a ≈1 nm highly defective layer with a higher oxygen concentration on the activated NiFe(2)O(4) and P-doped NiFe(2)O(4) nanoparticle surfaces (than that in bulk), which improves the charge transfer kinetics toward OER. Such surface species are not formed on Ni(1.5)Fe(1.5)O(4). Overall, this study provides a mechanistic understanding of the role of Fe, P, and Ni in forming active oxygen species in the Ni-based spinels toward OER.