Manipulation of Antiferromagnetic Metal Phase in Nd(1-x)Ce(x)NiO(3) by Epitaxial Strain

通过外延应变调控Nd(1-x)Ce(x)NiO(3)中的反铁磁金属相

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Abstract

Antiferromagnetic metals (AFMs) are potential candidates for spintronics application owing to their insensitivity to external magnetic perturbations. However, the scarcity of AFM in complex oxide presents a significant challenge in tuning their critical properties, thereby impeding the exploration of emergent phenomena and the advancement of practical applications. Quite recently, an AFM ground state is discovered in Nd(1-x)Ce(x)NiO(3), an oxide whose undoped parent counterpart exhibits metal-insulator transition dependent on temperature. Herein, the engineering of the AFM state by epitaxial strain in Nd(1-x)Ce(x)NiO(3) (0 ≤ x ≤ 0.07) films is demonstrated, where both Néel temperature and the metal-metal transition temperature exhibit significant response. Particularly in the 5% Ce-doping counterpart (Nd(0.95)Ce(0.05)NiO(3)), a suppression of the structural transition driven by compression strain causes a transition of the electronic/magnetic ground state from the AFM to paramagnetic metal. The O-K edge X-ray absorption spectra (XAS) reveal that strain plays a crucial role in modulating the magnetic ground state through modifying Ni─O hybridization. This work demonstrates the successful engineering of the electronic/magnetic states of AFM through epitaxial strain, providing a vital roadmap for the development of nickelate-based AFM devices.

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