Environmentally Friendly and Simple Recycling of Titanium Alloy Scrap via Deoxygenation with Hybrid Hydrogen Plasma Arc

利用混合氢等离子弧脱氧法对钛合金废料进行环保简便的回收利用

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Abstract

The potential of hydrogen plasma arc technology for the efficient deoxygenation and recycling of titanium alloy scrap is explored. The results of thermodynamic analysis reveal that hydrogen plasma is suitable for oxygen removal. The intermediate stages of the deoxygenation process are sequentially analyzed, showing that the hydrogen plasma arc primarily facilitated the reduction and dissolution of oxides as well as eliminated interstitial oxygen. The experimental results demonstrate that the deoxygenation dynamics are governed by the interaction between the hydrogen partial pressure and the surface area of the hydrogen plasma arc irradiation range. Furthermore, the results of the detailed characterization of the recycled titanium alloys indicate that hydrogen plasma arc technology not only reduces the oxygen content to levels compliant with industrial standards for Ti-6Al-4 V but also substantially enhances the tensile strength and ductility of Ti-6Al-4 V compared with those of conventional cast titanium alloys. The results of microstructural analysis show that hydrogen tends to concentrate in the β phase, whereas oxygen is predominantly found in the α phase. These findings highlight the effectiveness of hydrogen plasma arc technology, which offers environmental benefits and improves the performance of the resulting material, indicating its promise as a solution for titanium recycling.

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