Abstract
The α-c (α-FAPbI(3)) has been extensively employed in the fabrication of high-efficiency perovskite solar cells, yet heavily relied on multiple additives in upscalable fabrication in air. In this work, a simple α-FAPbI(3) ink is developed for the blade-coating fabrication of phase-pure α-FAPbI(3) in ambient air free from any additives containing extrinsic ions. The introduction of 2-imidazolidinone (IMD) to the FAPbI(3) precursor inks leads to the formation of intermediate phases that change the phase transition pathway from δ-FAPbI(3) to α-FAPbI(3) by tilting the PbI(6) octahedrons with strong coordination to Pb(2+). Furthermore, the IMD ligands in the intermediate phase gradually escape from the perovskite film during the annealing, leaving a phase-pure α-FAPbI(3) film vertically grown with large grains. Consequently, the small-sized PSCs fabricated with blade-coated α-FAPbI(3) film achieve an efficiency of up to 23.14%, and the corresponding mini-module yields an efficiency of 19.66%. The device performance is among the highest reported for phase-pure α-FAPbI(3) PSCs fabricated in the air without non-native cations or chloride additives, offering a simple and robust fabrication approach of phase-pure α-FAPbI(3) films for PV application.