Material Composition Design for Long-Term Stability of Solid Oxide Fuel Cell Based on Creep Damage and Failure Probability

基于蠕变损伤和失效概率的固体氧化物燃料电池长期稳定性材料组成设计

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Abstract

Electrode degradation represents a primary factor contributing to the performance decay. The composition design of electrode materials directly determines the long-term stability of solid oxide fuel cell (SOFC) under high-temperature service conditions. This paper focuses on the effect of anode and cathode material compositions on the creep damage and failure probability of SOFCs after 50,000 h creep. The results reveal an optimal Ni content range for mechanical integrity. Specifically, increasing the Ni volume fraction from 30% to 50% results in a reduction in the creep damage. In contrast, extending the increase to 60-70% causes a general reversal of this trend, with the creep damage showing an overall increase. The paper concludes that the Ni volume fraction of 50-60% is appropriate to maintain the long-term operation of SOFC. The La(0.8)Sr(0.2)MnO(3) (LSM) volume fraction with higher electrochemical efficiency can be selected for cathode manufacturing. This study provides a reference for developing long-life SOFC electrode materials.

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