Abstract
Cobalt oxide (Co(3)O(4)) serves as a promising electrocatalyst for oxygen evolution reactions (OER) in water-electrolytic hydrogen production. For more practical applications, advances in dry-deposition processes for the high-throughput fabrication of such Co(3)O(4) electrocatalysts are needed. In this work, a thermal metal-organic deposition (MOD) technique is developed to form Co(3)O(4) deposits on microscale-diameter carbon fibers constituting a carbon fiber paper (CFP) substrate for high-efficiency OER electrocatalyst applications. The Co(3)O(4) electrocatalysts are deposited while uniformly covering the surface of individual carbon fibers in the reaction temperature range from 400 to 800 °C under an ambient Ar atmosphere. It is found that the microstructure of deposits is dependent on the reaction temperature. The Co(3)O(4) electrocatalysts prepared at 500 °C and over exhibit values of 355-384 mV in overpotential (η(10)) required to reach a current density of 10 mA cm(-2) and 70-79 mV dec(-1) in Tafel slope, measured in 1 M KOH aqueous solution. As a result, it is highlighted that the improved crystallinity of the Co(3)O(4) electrocatalyst with the increased reaction temperature leads to an enhancement in electrode-level OER activity with the high electrochemically active surface area (ECSA), low charge transfer resistance (R(ct)), and low η(10), due to the enhanced electrical conductivity. On the other hand, it is found that the inherent catalytic activity of the surface sites of the Co(3)O(4), represented by the turnover frequency (TOF), decreases with reaction temperature due to the high-temperature sintering effect. This work provides the groundwork for the high-throughput fabrication and rational design of high-performance electrocatalysts.