Abstract
In this study, we have investigated heterostructural TiO(2)/BiVO(4) anodes to determine the effect of the amount and form of BiVO(4) nanoparticles on TiO(2) on the response of photoanodes under UV and visible illumination. BiVO(4) nanopowders were prepared and annealed at temperatures ranging from 200 to 500 °C. Structural and optical characterization indicates that as the annealing temperature is increased, a phase transition from a weakly ordered to a dominant monoclinic BiVO(4) phase is observed, which is accompanied by an increase in visible light absorption. Subsequently, the most crystalline powder was utilized to deposit BiVO(4) on nanostructured TiO(2) either as a compact overlayer (drop-casting) or as a progressively grown nanoparticle (TiO(2)@S series) in the successive ionic layer adsorption and reaction process (SILAR). Photoelectrochemical measurements were performed, revealing a morphology-dependent photocurrent response under UV and visible illumination. A further increase in the number of cycles systematically increases the photocurrent in the visible light range while limiting the response to UV radiation. The TiO(2)@d photoanode demonstrates the highest relative activity within the visible range; however, it also generates the lowest absolute photocurrent, indicating the presence of significant transport and recombination losses within the thick BiVO(4) layer. The results demonstrate that the presence of BiVO(4) nanoparticles on TiO(2) exerts a substantial influence on the separation of charge between semiconductors and the synergistic utilization of photons from the UV and visible ranges. This research yielded a proposed scheme of mutual band arrangement and charge carrier transfer mechanism in TiO(2)@BiVO(4) heterostructures.