Abstract
From the viewpoint of green chemistry and sustainable development, it is of great significance to synthesize chemicals from CO₂ as C₁ source through C-N bond formation. During the past several decade years, many studies on C-N bond formation reaction were involved, and many efforts have been made on the theory. Nevertheless, several great challenges such as thermodynamic limitation, low catalytic efficiency and selectivity, and high pressure etc. are still suffered. Herein, recent advances are highlighted on the development of catalytic methods for chemical fixation of CO₂ to various chemicals through C-N bond formation. Meanwhile, the catalytic systems (metal and metal-free catalysis), strategies and catalytic mechanism are summarized and discussed in detail. Besides, this review also covers some novel synthetic strategies to urethanes based on amines and CO₂. Finally, the regulatory strategies on functionalization of CO₂ for N-methylation/N-formylation of amines with phenylsilane and heterogeneous catalysis N-methylation of amines with CO₂ and H₂ are emphasized.