Abstract
Long-standing experimental data on the elastic modulus of end-linked poly(dimethylsiloxane) (PDMS) networks are employed to corroborate the validity of the Miller-Macosko theory (MMT). The validity of MMT is also confirmed by molecular dynamics (MD) simulations that mimic the experimentally realized networks. It becomes apparent that for a network formed from bulk, where the fractions of the loops are small, it is sufficient to account for the topological details of a reference tree-like network, i.e., for its degree of completion, junction functionalities, and trapped entanglements, in order to practically predict the modulus. However, a mismatch is identified between the MMT and MD simulations in relating the fraction of the soluble material to the extent of reaction. A large contribution of entanglements to the modulus of PDMS networks prepared with short precursor chains is presented, suggesting that the elastic modulus of commonly used end-linked PDMS networks is in fact entanglement-dominated.