Laser-Assisted Production of Carbon-Encapsulated Pt-Co Alloy Nanoparticles for Preferential Oxidation of Carbon Monoxide

激光辅助生产碳包覆 Pt-Co 合金纳米粒子用于一氧化碳优先氧化

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作者:Gema Martinez, Ana Malumbres, Angela Lopez, Reyes Mallada, Jose L Hueso, Jesus Santamaria

Abstract

C-encapsulated highly pure PtxCoy alloy nanoparticles have been synthesized by an innovative one-step in-situ laser pyrolysis. The obtained X-ray diffraction pattern and transmission electron microscopy images correspond to PtxCoy alloy nanoparticles with average diameters of 2.4 nm and well-established crystalline structure. The synthesized PtxCoy/C catalyst containing 1.5 wt% of PtxCoy nanoparticles can achieve complete CO conversion in the temperature range 125-175°C working at weight hourly space velocities (WHSV) of 30 L h-1g-1. This study shows the first example of bimetallic nanoalloys synthesized by laser pyrolysis and paves the way for a wide variety of potential applications and metal combinations.

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