Abstract
Remarkable improvement in the perovskite solar cell efficiency from 3.8% in 2009 to 25.5% today has not been a cakewalk. The credit goes to various device fabrication and designing techniques employed by the researchers worldwide. Even after tremendous research in the field, phenomena such as ion migration, phase segregation, and spectral instability are not clearly understood to date. One of the widely used techniques for the mitigation of ion migration is to reduce the defect density by fabricating the high-quality perovskite thin films. Therefore, understanding and controlling the perovskite crystallization and growth have become inevitably crucial. Some of the latest methods attracting attention are controlling perovskite film morphology by modulating the coating substrate temperature, antisolvent treatment, and solvent engineering. Here, the latest techniques of morphology optimization are discussed, focusing on the process of nucleation and growth. It can be noted that during the process of nucleation, the supersaturation stage can be induced faster by modifying the chemical potential of the system. The tailoring of Gibbs free energy and, hence, the chemical potential using the highly utilized techniques is summarized in this minireview. The thermodynamics of the crystal growth, design, and orientation by changing several parameters is highlighted.