Separation of cyclotron-produced cobalt-55/58m from iron targets using cation exchange chromatography with non-aqueous solvents and extraction chromatography

利用非水溶剂阳离子交换色谱法和萃取色谱法从铁靶中分离回旋加速器产生的钴-55/58m。

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Abstract

Cobalt-55 and -58m form a theranostic pair that has relevant properties for cancer research. We report a cation exchange chromatography/extraction chromatography method that separates cyclotron-produced (55/58m)Co from (54/57)Fe in <1.5 h, recovers >85% Co and achieves [(55)Co]Co-NOTA and -DOTA AMA 89 ± 48 and 35 ± 7 MBq/nmol (EOB), respectively. Cobalt-55 and -58m were quantitatively labeled to functionalized NOTA at 106 and 50 MBq/nmol (EOB), respectively, corroborating measured AMA. This method is faster than previously published methods and achieves better [(55/58m)Co]Co-NOTA and -DOTA AMA.

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