Flower-Like MoSe2/MoO2 Composite with High Capacity and Long-Term Stability for Lithium-Ion Battery

用于锂离子电池的高容量和长期稳定性的花状 MoSe2/MoO2 复合材料

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作者:Qiuyan Hao, Guoliang Cui, Yan Zhao, Zhumabay Bakenov

Abstract

A simple method is developed for the preparation of MoSe2/MoO2 composite with a flower-like structure for high-performance lithium-ion batteries (LIBs). MoSe2 could lead to fast and facile movement of Li+ due to its larger interlayer spacing. Meanwhile, MoO2 could protect the lamellar structure of MoSe2 from being destroyed in the charging/discharging processes to maintain the required active surface to electrolytes. In addition, the flower-like structure of the composite could effectively alleviate the volume expansion during charging/discharging. As LIBs are anode material, MoSe2/MoO2 composite demonstrates an excellent specific discharge capacity of 1042 mAh g-1 after 100 cycles at 0.1 A g-1, which is attributed to the synergistic effects of MoSe2 and MoO2 in the composite.

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