Simple modification of basic dyes with bulky &symmetric WCAs for improving their solubilities in organic solvents without color change

使用大分子对称 WCA 对碱性染料进行简单改性,以提高其在有机溶剂中的溶解度且不发生颜色变化

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作者:Jeong Yun Kim, Tae Gyu Hwang, Sung Wun Woo, Jae Moon Lee, Jin Woong Namgoong, Sim Bum Yuk, Sei-Won Chung, Jae Pil Kim

Abstract

A simple and easy solubility enhancement of basic dyes was performed with bulky and symmetric weakly coordinating anions (WCAs). The WCAs decreased the ionic character of the dyes by broadening the partial charge distribution and causing a screening effect on the ionic bonding. This new modification with WCAs has advantages in that it has no influence on the optical properties of the dyes. The solubilities of unmodified and modified dyes were tested in several organic solvents. X-ray powder diffraction patterns of the dyes were measured. Color films were prepared with the dyes and their color loci were analyzed to evaluate the optical properties. By the modification with WCAs, commercial basic dyes showed sufficient solubilities for be applied to various applications while preserving their superior optical properties.

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