Types of Component Interfaces in Metal Matrix Composites on the Example of Magnesium Matrix Composites

以镁基复合材料为例,探讨金属基复合材料中各组分界面类型

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Abstract

In this paper, a summary of investigations of the microstructure of cast magnesium matrix composites is presented. Analyses of the interfaces between the reinforcing particles and the magnesium alloy matrices were performed. Technically pure magnesium and four various alloys with aluminum and rare earth elements (RE) were chosen as the matrix. The composites were reinforced with SiC and Ti particles, as well as hollow aluminosilicate cenospheres. Microstructure analyses were carried out by light, scanning, and transmission electron microscopy. The composites with the matrix of magnesium and magnesium-aluminum alloys with SiC and Ti particles exhibited coherent interfaces between the components. In the composites based on ternary magnesium alloy with Al and RE with Ti particles, a high-melting Al(2)RE phase nucleated on the titanium. Different types of interfaces between the components were observed in the composites based on the magnesium-rare earth elements alloy with SiC particles, in which a chemical reaction between the components caused formation of the Re(3)Si(2) phase. Intensive chemical reactions between the components were also observed in the composites with aluminosilicate cenospheres. Additionally, the influence of coatings created on the aluminosilicate cenospheres on the bond with the magnesium matrix was presented. A scheme of the types of interfaces between the components is proposed.

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