Operando X-ray absorption spectra and mass spectrometry data during hydrogenation of ethylene over palladium nanoparticles

钯纳米粒子催化乙烯加氢反应过程中的原位X射线吸收光谱和质谱数据

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Abstract

We report the series of Pd K-edge X-ray absorption spectra collected during hydrogenation of ethylene with variable ethylene/hydrogen ratio over carbon supported palladium nanoparticles. The data presented in this article includes normalized X-ray absorption spectra, k (2)-weighted oscillatory χ(k) functions extracted from the extended X-ray absorption fine structure (EXAFS) and k (2)-weighted Fourier-transformed EXAFS data, χ(R). Each spectrum is reported together with the hydrogen, ethylene and helium flow rates, adjusted during its collection. In addition, time evolution of the ratio of m/Z signals of 30 and 28 registered by online mass spectrometer is presented. The data analysis is reported in Bugaev et al., Catal. Today, 2019 [1].

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