Geochemical Distribution and Environmental Risks of Radionuclides in Soils and Sediments Runoff of a Uranium Mining Area in South China

华南某铀矿区土壤及径流沉积物中放射性核素的地球化学分布及其环境风险

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Abstract

Uranium mining activities have contributed to the distribution and uptake of radionuclides, which have increased the active concentrations of natural radionuclides in environmental media, causing elevated human health risks. The present study aims to assess the spatial distribution characteristics of natural radionuclides in the surface soils and river sediments of the typical granite uranium mining area in South China, as well as investigate the geochemical features of natural radionuclides in the soil and sediments to understand their migration processes. The activity concentrations for (238)U, (226)Ra, (232)Th, and (40)K ranged from 17-3925 Bq/kg, 50-1180 Bq/kg, 29-459 Bq/kg, and 240-1890 Bq/kg, respectively. The open-pit mining areas and tailings pond locations exhibited the highest concentrations of activity for all these radionuclides. This distribution points to an elevated potential health risk due to radiological exposure in these specific areas. Additionally, the values of radium equivalent activity (Ra(eq)) and annual gonadal dose equivalent (AGDE) in those areas were higher than the limits recommended by ICRP (2021). (238)U and (226)Ra have a significant correlation (0.724), and the cluster analysis was showing a statistically meaningful cluster below 5 indicated that they have similar behavior during parent rock weathering and watershed erosion, and the distribution of (232)Th and (40)K were influenced by the addition of rock types. The activity ratios of (226)Ra/(238)U, (226)Ra/(232)Th, (238)U/(40)K, and (226)Ra/(40)K variation indicated that (40)K more mobile than (226)Ra and (238)U, U(VI) was reduced to U(IV) by organic matter in the downstream area and re-entered into the sediment during the sediment surface runoff in the small watershed of the uranium ore open-pit mining area. Therefore, it is necessary to further seal up and repair the tailings landfill area.

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