Abstract
The flammability and volatility of conventional lithium hexafluorophosphate (LiPF(6))-based electrolytes with organic carbonate solvents remain critical issues to the safety and thermal stability of lithium-ion batteries (LIBs). This study investigates the incorporation of phosphate-based additives including ammonium dihydrogen phosphate (ADP), trimethyl phosphate (TMP), and trimethyl phosphite (TMPi) into LiPF(6) electrolytes for improving the ionic conductivity, safety, and electrochemical performance of LIBs. Self-extinguishing time (SET) measurements demonstrated that the ADP-based LiPF(6) electrolyte significantly reduced flammability, achieving a shorter SET of 04 min 53 s, compared to 12 min for the pristine LiPF(6) electrolyte. The ADP-based LiPF(6) electrolyte possessed the highest ionic conductivity (14.08 mS·cm(-1)) with an excellent lithium-ion transference number of 0.0076. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (C-V) analyses demonstrated that ADP lowered interfacial resistance and stabilized long-term cycling behavior. In particular, the 1% ADP-based LiPF(6) electrolyte maintained improved charge-discharge profiles and Coulombic efficiency over 200 cycles. These results highlight ADP's dual functionality in suppressing gas-phase flammability and enhancing condensed-phase electrochemical stability, making it a promising candidate for next-generation, high-safety, high-performance LIB electrolytes.