Abstract
We investigate the structure and dynamics of proton solvation structures in mixed water/dimethyl sulfoxide (DMSO) solvents using two-color mid-infrared femtosecond pump-probe spectroscopy. At a water fraction below 20%, protons are mainly solvated as (DMSO-H)(+) and (DMSO-H)(+)-H(2)O structures. We find that excitation of the OH-stretch vibration of the proton in (DMSO-H)(+)-H(2)O structures leads to an ultrafast contraction of the hydrogen bond between (DMSO-H)(+) and H(2)O. This excited state relaxes rapidly with T(1) = 95 ± 10 fs and leads in part to a strong local heating effect and in part to predissociation of the protonated cluster into (DMSO-H)(+) and water monomers.