Abstract
Sulfur, as a crucial chemical raw, poses increased combustion-explosion risks when mixed with other hazardous substances due to its dual nature as both an oxidant and a reducing agent. Additionally, sulfur-induced combustion and explosions can result in environmental pollution. Combustion-explosion suppression technology plays a crucial role in industrial production by effectively preventing hazardous chemical explosion incidents. This research investigates the combustion-explosion suppression of black powder, a common hazardous chemical containing sulfur, by utilizing two solid-based blast suppressants, NH(4)H(2)PO(4) and NaHCO(3). On this basis, examining changes in the oxidation states of sulfur and explaining the mechanisms of combustion-explosion suppression through the examination of combustion-explosion products. Additionally, numerical calculations are employed to analyze the evolution patterns of gaseous and solid-phase products throughout the entire combustion-explosion process. Research indicates that NaHCO(3) exhibits a more effective combustion-explosion suppression effect on black powder compared to NH(4)H(2)PO(4), which attributed to the valence state transformation of sulfur and the reduction of carbon oxidation. Furthermore, with the enhancement of combustion-explosion suppression effect, K(2)S, which a pollutes the environment, is gradually transform converted into potassium fertilizer K(2)SO(4), which benefits plants. These results offer new insights into the research of combustion-explosion suppression of sulfur-containing substances and environmental protection strategies.