Bioderived copolymer alternatives to poly(styrene-co-maleic anhydride) via RAFT-mediated copolymerization

通过RAFT介导共聚法制备生物基共聚物替代聚(苯乙烯-马来酸酐共聚物)

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Abstract

Poly(styrene-co-maleic anhydride) (SMAnh) is a petroleum-based copolymer with desirable properties that afford utility in both industrial and academic fields. The reversible addition-fragmentation chain transfer (RAFT)-mediated polymerization of the bioderived comonomers, indene and itaconic anhydride, was explored using three chain transfer agents with varying activity, and generally well-controlled (Đ < 1.40) polymerizations were observed.

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