Thermal Stability of Highly Filled Cellulosic Biocomposites Based on Ethylene-Vinyl Acetate Copolymer

基于乙烯-醋酸乙烯酯共聚物的高填充纤维素生物复合材料的热稳定性

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作者:Pavel Gennadievich Shelenkov, Petr Vasilievich Pantyukhov, Svetlana Vladimirovna Aleshinskaya, Alexander Andreevich Maltsev, Zubarzhat Rafisovna Abushakhmanova, Anatoly Anatolievich Popov, Jose Javier Saavedra-Arias, Matheus Poletto

Abstract

The effect of plant-based fillers on thermal resistance in highly filled biocomposites based on ethylene-vinyl acetate copolymer (EVA) was studied. Wood flour and microcrystalline cellulose were used as fillers. It was shown that the introduction of microcrystalline cellulose into EVA did not affect the thermal stability of the polymer matrix. In contrast, the introduction of wood flour into EVA led to a significant increase in the thermal stability of the entire biocomposite. Oxidation induction time increased from 0 (pure EVA) to 73 min (EVA + wood flour biocomposites). The low-molecular weight phenolic compounds contained in wood flour are likely able to diffuse into the polymer matrix, exerting a stabilizing effect. The discovered stabilizing effect is a positive development for expanding the possibilities of technological processing of biocomposites, including multiple processing.

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