Abstract
Three classes of organosilicas (DMO, OMOs and PMOs) containing immobilized multi-hydroxyl bis-(quaternary ammonium) iodide salts were prepared and tested in the cycloaddition of CO(2) and epoxides. Owing to its higher surface area, pore volume and optimum nucleophilicity of the iodide ion, OMO-2 with two hydroxyl groups was found to be the most active catalyst. For substrates that are easy to activate such as propylene oxide, 1,2-epoxybutane and epichlorohydrin, excellent yields and selectivities were obtained under mild reaction conditions (0.5 MPa CO(2), 50 °C and 10-15 h). Moreover, OMO-2 showed very good catalytic properties (yield ≥ 93% and selectivity ≥ 98%), and excellent chemical and textural stability in the synthesis of 1,2-butylene carbonate over 5 cycles.