Abstract
In desiccated films, particularly with old paintings, molecular bonds may break to create intricate patterns of macroscopic cracks. The resulting directions of the cracks quantifiably enable an evaluation of the entropy and degree of disorder in the network. Experimental tests on prepared samples and a two-interacting-variables model allow the evolution of entropy to be tracked. Calculations were performed, primarily using data from the painting Girl with a Pearl Earring by Vermeer, revealing that the left side of the girl's face features a crack structure with higher entropy (or less order) than the right side. Other old paintings were considered. The extrapolation of experiments to these old paintings confirms that saturation still is not reached.