Abstract
To overcome the problem of Cr(2)O(3) and Al(2)O(3) inclusions in CuCr50 alloy prepared by aluminothermic reduction method, in this paper, a novel methodology for strengthening metal-slag separation through in situ slagging is proposed. CuCr50 alloys were prepared by metallothermic reduction using Al and Al-Mg as reducing agents, and the physical properties of the slag, such as viscosity, density, and surface tension, were adjusted by controlling the proportion of CaO in the slagging agent in the raw material to achieve good separation of the slag-metal. The results show that with the ratio of CaO increased, CaO and MgO were coupled to make slag, which combined with Cr(2)O(3) and Al(2)O(3) to form CaCr(2)O(4), MgCr(2)O(4), and CaAl(4)O(7) in the slag, thus reducing the content of impurities in the alloy. When RCaO/(CaO + Al(2)O(3) + MgO) = 20%, the Cr content ranged from 46.61% to 47.09%, the inclusions accounted for 1.60%, the Cr particle size was refined to 20 µm, the number of Cr spherical crystals accounted for 9.88%, the conductivity reached 14.96 MS/m, and the hardness reached 100.23 HB. After heat treatment, the Cr phase was refined in the alloy, the conductivity increased from 14.96 MS/m to 18.27 MS/m, and the hardness increased from 100.23 HB to 103.1 HB. This method is expected to provide an effective method for the preparation of CuCr50 contact materials.