Discovery of methyl silane and confirmation of silyl cyanide in IRC +10216

IRC +10216 中甲基硅烷的发现和氰化硅的确认

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Abstract

We report the discovery in space of methyl silane, CH(3)SiH(3), from observations of ten rotational transitions between 80 and 350 GHz (J(u) from 4 to 16) with the IRAM 30 m radio telescope. The molecule was observed in the envelope of the C-star IRC +10216. The observed profiles and our models for the expected emission of methyl silane suggest that the it is formed in the inner zones of the circumstellar envelope, 1-40 R(*), with an abundance of (0.5-1) × 10(-8) relative to H(2). We also observed several rotational transitions of silyl cyanide (SiH(3)CN), confirming its presence in IRC +10216 in particular, and in space in general. Our models indicate that silyl cyanide is also formed in the inner regions of the envelope, around 20 R(*), with an abundance relative to H(2) of 6×10(-10). The possible formation mechanisms of both species are discussed. We also searched for related chemical species but only upper limits could be obtained.

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