Abstract
Experimental levels of the configuration 3d(n) 4p in the second spectra of the iron group were compared with corresponding calculated values. Besides the electrostatic and spin-orbit interactions the α, β and T corrections were considered in the individual and general treatments. The insertion of the parameters β and T improved the results by about 21 percent. The rms error on fitting 703 levels by means of 21 free interaction parameters was 231 cm(-1). Altogether 912 energy levels were predicted.